Aa_oxid R_const*T/(0.5*F_const)*log(10) "Anodic Tafel slope solvent oxidation"
Ac_Hred -R_const*T/(0.5*F_const)*log(10) "Cathodic Tafel slope proton reduction"
Ac_Mndep -R_const*T/(0.5*F_const)*log(10) "Cathodic Tafel slope manganese deposition"
av_oxid 1e6[1/m] "Specific surface area of conductive carbon black at which solvent oxidation takes place"
cH_ref 100[mol/m^3] "Reference proton concentration"
cMn_ref 10[mol/m^3] "Reference manganese concentration"
cl_ref 1000[mol/m^3] "Reference electrolyte salt concentration"
Crate 1/3 "C rate"
D_H 5e-9[m^2/s] "Diffusion coefficient of protons"
D_H2O 3e-9[m^2/s] "Diffusion coefficient of water"
D_Mn 7.2e-10[m^2/s] "Diffusion coefficient of manganese ion"
Eeq_H 1.5[V] "Reference equilibrium potential of proton reduction vs Li(s)/Li+"
Eeq_Mn 2.5[V] "Reference equilibrium potential of manganese vs Li(s)/Li+"
Eeq_oxid 4.2[V] "Equilibrium potential of solvent oxidation vs Li(s)/Li+"
epsl_pos 0.4 "Electrolyte volume fraction in positive electrode"
epsl_sep 0.4 "Electrolyte volume fraction in separator"
epss_pos0 0.4 "Initial electrode (LMO) volume fraction in positive electrode"
i0_oxid 10[uA/m^2] "Exchange current density solvent oxidation"
i0_ref_H 1e-18[A*m/mol]*cH_ref "Exchange current density proton reduction at cH_ref"
i0_ref_Mn 1.0e-11[A*m/mol]*cMn_ref "Exchange current density manganese reduction at cMn_ref"
i0_ref_lmo 10[A/m^2] "Exchange current density at 50% lithiation in LMO electrode material"
kproton 2e-11[m/s] "Rate constant of LMO dissolution by protons"
kwater 7e-10[m^6/mol^2/s] "Rate constant of electrolyte salt concentration from water"
L_pos 50[um] "Positive electrode thickness"
L_sep 50[um] "Separator thickness"
ns 0.10 "Adjust factor for diffusion coefficient in LMO"
rp_lmo 5[um] "Radius of LMO electrode particles"
sigmas_pos 10[S/m] "Effective positive electrode conductivity"
T 55[degC] Temperature
Vhigh_over 4.5[V] "Higher cut-off voltage at overcharge"
Vhigh 4.5[V] "Higher cut-off voltage"
Vlow 3.6[V] "Lower cut-off voltage"
Vm 4.1e-5[m^3/mol] "Molar volume of LMO"
zH 1 "Charge of protons"
zMn 2 "Charge of manganese ion"