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The chlor-alkali membrane process is one of the largest in industrial electrolysis with the production of roughly 40 million metric tons of both chlorine and caustic soda per year. Chlorine is used predominantly for the production of vinyl chloride monomer, which in turn is used for the ... Mehr lesen
Voltammetry is modeled at a microelectrode of 10um radius. In this common analytical electrochemistry technique, the potential at a working electrode is swept up and down and the current is recorded. The current-voltage waveform ("voltammogram") gives information about the reactivity and ... Mehr lesen
In small PEM fuel cell systems (in the sub-100 W range) no active devices for cooling or air transport are normally used. This is due to the desire to minimize parasitic power losses from pumps and fans, and to reduce the system complexity, size, and cost. The reactants at the cathode ... Mehr lesen
This example extends the Fuel Cell Cathode tutorial to also include liquid water transport in the oxygen electrode. Liquid water is produced using a user-defined expression for vapor condensation, depending on the relative humidity level in the gas phase. An experimental capillary ... Mehr lesen
Digital Rock technology utilizes high-resolution imaging techniques, such as SEM and X-ray CT, to characterize the pore structures of rock cores. This approach enables pore-scale modeling of reservoir rocks, offering valuable insights into pore morphology, connectivity, and fluid ... Mehr lesen
This tutorial demonstrates how to use stationary polarization data to perform parameter estimation of a polymer electrolyte membrane fuel cell (PEMFC) model. The model, defining a 5-layer membrane electrode assembly (MEA) is two-dimensional and includes electronic and ionic charge ... Mehr lesen
A fuel cell unit cell is modeled using the full Butler-Volmer expression for the anodic and cathodic charge transfer reactions. The anodic and cathodic overpotentials depend on the local ionic and electronic potentials, which are obtained from the charge balance equations for ionic and ... Mehr lesen
This tutorial models how the relative humidity of the inlet gases impacts the performance of a low-temperature polymer electrolyte membrane-electrode assembly. The model includes humidity-dependent ionomer (electrolyte) conductivities, gas phase mass transport and water ionomer ... Mehr lesen
In this model of an ammonia-fed solid oxide fuel cell, the required hydrogen is supplied through endothermic thermal decomposition of ammonia. The model includes the full coupling between the mass balances and gas flow in the H2 and O2 gas diffusion electrodes, the momentum balances in ... Mehr lesen
A bipolar membrane consists of one anion-selective, and one cation-selective membrane, in contact with each other. The combined cation and anion selectivity makes the bipolar membrane highly impermeable to all ions, with the exception of H+ and OH- which are formed by water splitting ... Mehr lesen