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For an electrochemical reaction to occur, the reacting species usually needs to adsorb to the electrode surface before undergoing reduction or oxidation, after which the resulting product species desorbs back into the electrolyte. If the rate of adsorption or desorption is slow in ... Mehr lesen
This example models the deposition of an inductor coil in 3D. The geometry includes the extrusion of the deposition pattern into an isolating photoresist mask, and a diffusion layer on top of the photoresist. The mass transfer of copper ions in the electrolyte has a major impact on the ... Mehr lesen
This model describes the evaporation of a droplet that consists of concentrated solution of acetone and water. It accounts for the coupled phenomena of chemical species transport and heat transfer over phase boundaries (liquid-gas boundary) as well as for multiphase flow. The droplet ... Mehr lesen
Atmospheric corrosion occurs when metallic structures are exposed to humid air forming a thin electrolyte film in the range of up to a few hundred micrometers. The model presented here accounts for charge transport as well mass transport involving 10 species and 6 homogeneous ... Mehr lesen
The hydrolysis of propylene oxide into propylene glycol is an important chemical process with 400,000 metric tons produced worldwide each year. Propylene glycol finds wide application as a moisturizer in foods, pharmaceuticals, and cosmetics. In this example, the startup phase of a ... Mehr lesen
Crystallization is a key separation process in e.g. pharmaceuticals production. It is the process by which a chemical species is separated from solution by forming a crystal. To achieve the required product properties, control over the crystal particle size distribution is necessary. ... Mehr lesen
This model reproduces the NiCd battery model and the results presented in De Vidts' and White's paper from 1995. Ref: P. De Vidts, R. E. White, “Mathematical Modeling of a Nickel-Cadmium Cell: Proton Diffusion in the Nickel Electrode”, J. Electrochem. Soc, Vol. 142, No. 5, May 1995. Mehr lesen
A bipolar membrane consists of one anion-selective, and one cation-selective membrane, in contact with each other. The combined cation and anion selectivity makes the bipolar membrane highly impermeable to all ions, with the exception of H+ and OH- which are formed by water splitting ... Mehr lesen
The model simulates atmospheric corrosion of a galvanic couple, comprising of an Al-Co-Ce metallic coating and an aluminum alloy, which is in contact with electrolyte film of 100 micrometer thickness. The corrosion inhibitors are released from the metallic coating and are transported ... Mehr lesen
Corrosion induced due to alternating current (AC) is evident in the oil and gas industry, particularly when a pipeline is in close proximity to the high power transmission lines. A numerical model presented here first evaluates the effect of direct current (DC) applied potential on ... Mehr lesen