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Deposition of metallic lithium on the negative electrode in preference to lithium intercalation is known to be a capacity loss and safety concern for lithium-ion batteries. Harsh charge conditions such as high currents (fast charging) and/or low temperatures can lead to lithium plating. ... Mehr lesen
This tutorial uses a “black-box” approach to define a battery model based on a small set of lumped parameters, assuming no knowledge of the internal structure or design of the battery electrodes, or choice of materials. The input to the model is the battery capacity, the initial state ... Mehr lesen
Electrochemical supercapacitors feature relatively higher energy densities than conventional capacitors. With several advantages, such as fast charging, long charge–discharge cycles, and broad operating temperature ranges, electrochemical supercapacitors have found wide applications in ... Mehr lesen
Electrodialysis is a separation process for electrolytes based on the use of electric fields and ion selective membranes. Some common applications of the electrodialysis process are: Desalination of process streams, effluents, and drinking water pH regulation in order to remove acids ... Mehr lesen
Diffusion-induced stress in lithium-ion battery electrode materials can occur as a result of compositional inhomogeneities during lithium intercalation in the host material particles. These stresses are important since the electrode host material can undergo significant volume changes ... Mehr lesen
The engine block of a car includes a cooling jacket to remove excess heat from combustion. The cooling jacket consists of open spaces in the cylinder block and the cylinder head. When the engine is running, a coolant fluid is pumped through the jacket to keep the engine from overheating. ... Mehr lesen
Copper electrowinning is the process of copper extraction from an electrolyte solution and its deposition at the cathode surface, by passing an external current through the electrolytic cell and using an insoluble anode. During the process, oxygen bubbles are generated at the anode ... Mehr lesen
Tubular reactors are often used in continuous large-scale production, for example in the petroleum industry. One key design parameter is the conversion, or the amount of reactant that reacts to form the desired product. In order to achieve high conversion, process engineers optimize the ... Mehr lesen
Removing halogen groups from hydrocarbons is an important reaction step in several chemical processes. One application is water purification. Other examples involve organic synthesis, where the removal of halogen groups serves as a starting point for carbon-carbon coupling reactions. ... Mehr lesen
In diesem Beispiel wird die Freisetzung eines Medikaments aus einer Biomaterialmatrix in beschädigtes Zellgewebe modelliert. Konkret liefert eine Nervenleitschiene ein regenerierendes Medikament an geschädigte Nervenenden. Das Modell beinhaltet eine detaillierte Kinetik der ... Mehr lesen