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Towards a Microscopic Model for Species Transport in Lithium-Sulphur Cells

Geraint Minton [1], Rajlakshmi Purkayastha [1], Laura O’Neill [1], Sylwia Walus [1], Mark Wild [1], Monica Marinescu [2], Teng Zhang [2], Gregory Offer [2],
[1] Oxis Energy Ltd, Abingdon, Oxfordshire, UK
[2] Mechanical Engineering Department, Imperial College, London, UK

Lithium-sulphur (Li-S) batteries have the potential to surpass the energy storage capability of Li-ion batteries due to their high theoretical gravimetric energy density of 2700 Wh/kg. However, the processes which drive the system behaviour are much more complex than those in a Li-ion cell, meaning that controlling them to realise energy densities much above 350 Wh/kg is challenging. In a Li ...

Steady-state simulation of mono-valent ion distributions within a nanofluidic channel

W. Booth[1], J. Schiffbauer[1], J. Fernandez[2], K. Kelley[3], A. Timperman[3], and B. Edwards[1]

[1]Physics Department, West Virginia University, Morgantown, WV, USA
[2]Chemical Engineering Department, West Virginia University, Morgantown, WV, USA
[3]Chemistry Department, West Virginia University, Morgantown, WV, USA

The steady-state non-equilibrium distributions of two species of mono-valent ions around a charged nanofluidic channel have been examined. Large reservoirs were placed on either side of the nanoscale channel to simulate bulk concentration of ions in a fluid. Results from COMSOL Multiphysics simulations show that the effect of the potential bias across the nanochannel yields a significant ...

Topology Optimization of Lithium-Ion Battery Electrode Microstructure Morphology for Reduction of Damage Accumulation and Longevity of Battery Life - new

P. Clarke[1], R. Abedi[1]
[1]University of Tennessee Space Institute, Tullahoma, TN, USA

The ubiquitous commercial use of Lithium-Ion batteries (LIBs) has increased interest in their implementation into efficient energy storage systems for clean and renewable power sources and the electrical transportation industry. Unfortunately, LIBs are not yet technological mature to meet various commercial demands. Consider the following challenges for example,: (1) lower than desired effective ...

Zinc Corrosion in a Crevice

C. Taxén, and D. Persson
Swerea-Kimab, Stockholm, Sweden

Corrosion of metals in confined zones is a big industrial problem. The electrochemistry of such localized corrosion processes is complicated by the impact of the corrosion processes on the composition of the local solution. In the present problem, local interaction with the atmosphere causes uptake of O2 and CO2 and evaporation of water from the initially dilute NaCl-solution. This model ...

Improving Fuel Usage in Microchannel Based Fuel Cells

P. Fodor, and J. D'Alessandro
Dept. of Physics
Cleveland State University
Cleveland, OH

In this work a miniaturized fuel cell design based on microchannels, into which the liquid fuel and oxidizer streams are fed through T shaped connectors, is optimized for improved fuel usage. This particular design exploits the laminar nature of the fluid flow at small Reynolds numbers to keep the fuel and oxidizer confined in the vicinity of the corresponding electrodes without the need of a ...

Numerical Simulation of Carbon Steel Corrosion Exposed to Flowing NaCl Solutions Through an Annular Duct - new

A. Soliz[1], K. Mayrhofer[1], L. Caceres[2]
[1]Department of Interface Chemistry & Surface Engineering, Max-Planck-Institut für Eisenforschung, Düsseldorf, Germany
[2]Department of Chemical Engineering, University of Antofagasta, Antofagasta, Chile

A three-dimensional mathematical model under stationary conditions have been established to understand the corrosion of carbon steel cylindrical samples immersed in flowing NaCl solution through an annular duct. The migration, diffusion and convection mass transfer mechanisms were solved using the Nernst–Planck equation coupled to the Navier-Stokes equation. A corrosion model based on the mixed ...

Study of Tertiary Current Distributions on the Wafer in a Plating Cell

L. Tong[1]
[1]Keisoku Engineering System Co., Ltd,. Chiyoda-ku, Tokyo, Japan

The reciprocating paddle cell is a known practical method for depositing alloy films on wafer substrates. Recently, the mass transfer boundary layer within an industrial wafer plating cell was studied based on the measurement of limiting current. It was indicated that a shear-plate fluid agitation mechanism is capable of generating a thin (i.e.

Development of Tiny Fuel Cells for Micro-devices on the Basis of Simulation Results

S. Tominaka
International Center for Materials Nanoarchitectonics
National Institute for Materials Science

For the successful exploitation of microdevices such as microsensors, development of micro-power sources is strongly required. In this view, microbatteries and microfuel cells have been developed. Here the concept of on-chip fuel cells, which consist of all the components necessary for power generation integrated on a chip, is introduced. Then, in order to improve their performance, experimental ...

Magneto-hydrodynamic Flow in Electrolyte Solutions

M. Qin[1], and H. Bau[1]
[1]Department of Mechanical Engineering and Applied Mechanics, University of Pennsylvania, Pennsylvania, USA

The paper presents and compares two models for simulating magneto-hydrodynamic flow of RedOx electrolyte in a conduit patterned with circular pillars. The first model solves the coupled Nernst-Planck and Navier-Stokes equations subjected to Butler-Volmer electrode kinetics and provides detailed information on ions’ concentrations. The second model treats the electrolyte as a conductor, and ...

Lithium-Ion Battery Simulation for Greener Ford Vehicles

D. Bernardi
Ford Motor Company

Dr. Bernardi is a Research Engineer with Ford Motor Company in Dearborn, MI. Her research focuses on the analysis and simulation of electrochemical energy-storage and conversion systems. In particular, Dr. Bernardi develops mathematical models that predict system behavior and identify governing physicochemical processes. Experimental investigations support model development, analysis, and ...