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Mathematical Modeling of a Lithium Ion Battery

R. E. White[1], and Long Cai[2]
[1]R.E. White & Associates LLC, Columbia, South Carolina, USA
[2]Department of Chemical Engineering, University of South Carolina, Columbia, South Carolina, USA

The existing lithium ion battery model in COMSOL’s Multiphysics  software is extended to include the thermal effects. The thermal behavior of a lithium ion battery is studied during the galvanostatic discharge process with and without a pulse. The existing lithium ion battery model in COMSOL 3.5a is extended by adding an energy balance and the temperature dependence of properties of ...

2D Axisymmetric Simulation of Pulsed Electrochemical Machining (PECM) of Internal Precision Geometries

M. Hackert-Oschätzchen [1], M. Kowalick [1], R. Paul [1], M. Zinecker [1], D. Kuhn [1], G. Meichsner [2], A. Schubert [3],
[1] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany
[2] Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany
[3] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany; Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany

This study presents investigations on a developed process design for manufacturing internal precision geometries by pulsed electrochemical machining (PECM) with help of multiphysics simulations. Therefore, a 2D axisymmetric transient model was created. The considered physical phenomena are fluid dynamics, thermodynamics, electrodynamics, the formation and transport of hydrogen as well as ...

Modeling Galvanic Corrosion

E. Gutierrez-Miravete[1], M. Turner[2]
[1]Rensselaer at Hartford, Hartford, CT, USA
[2]General Dynamics-Electric Boat, Groton, CT, USA

Galvanic corrosion is encountered in marine applications because one often has dissimilar metal joints and seawater acts as an electrolyte. One metal acts predominantly as anode and undergoes material dissolution while the other acts predominantly as cathode and is the site where a cathodic reaction takes place. Assuming a stagnant electrolyte, the equation governing the distribution of ...

Heat Generation Modeling of Two Lithium Batteries: from the Cell to the Pack in COMSOL Multiphysics® Software

J. Stoudmann [1], R. Rozsnyo [1], T. Mackin [2], J. Dunning [2]
[1] Haute École du paysage, d'ingénierie et d'architecture, Genève, Switzerland
[2] California Polytechnic State University, San Luis Obispo, CA, USA

A thermal model to predict the heat generation during the charge and discharge of a battery pack is an essential tool to manage the thermal behavior, performance and life of the batteries. In this work, a battery cell is modeled in COMSOL Multiphysics® using the Batteries and Fuel Cells module.

Current Density Distribution and Material Removal Behavior on the Graphite/Iron-matrix Interface in Cast Iron Under Pulse Electrochemical Machining Conditions

O. Weber[1], R. Kollmannsperger[2], D. Bähre[2]
[1]Center for Mechatronics and Automatization, Saarbrücken, Germany
[2]Institute of Production Engineering, Saarland University, Saarbrücken, Germany

The Pulse Electrochemical Machining is especially suitable for the precise production of complex geometric contours with high precision and high surface quality demands in workpieces in series manufacturing. During this process, the negative structure of an electrode is copied to the workpiece without sub-surface damages. An adequate knowledge of the current density distribution and thus of the ...

Analysis of Electro-Thermal Hot Spot Formation in Li-Ion-Battery-Cells

W. Beckert[1], C. Freytag[1], T. Frölich[1], G. Fauser[1]
[1]Fraunhofer IKTS, Dresden, Germany

The presented model approach offers a computational efficient tool to analyze the influences of geometrical design details, material selection and operational conditions on the electro-thermal behavior of a full Li ion battery cell geometry. It considers typical aspects as anisotropic winding structure, electro-thermal coupling and nonlinear electrical characteristics for moderate computational ...

Simplified Multiphysics Model for All-Solid State Microbatteries

M.S. Nesro[1], I.M. Elfadel[1]
[1]Masdar Institute of Science and Technology, Masdar City, Abu Dhabi, UAE

Lithium microbatteries are replacing conventional power sources in many microsystems areas such as wireless sensors and biomedical monitors. In many of these applications, compact models of micro batteries are needed both at the microsystems design stage and at the real-time power management stage. These compact models are typically derived from physics-based discretized formulations. We have ...

CFD Modeling and Analysis of a Planar Anode Supported Intermediate Temperature Solid Oxide Fuel Cell - new

N. Lemcoff[1], M. Tweedie[2]
[1]Rensselaer Polytechnic Institute Hartford, Hartford, CT, USA
[2]Enthone, West Haven, CT, USA

A planar anode-supported intermediate temperature solid oxide fuel cell operating on syngas fuel at 750°C was analyzed in this study. The effects of varying syngas fuel inlet compositions on species and temperature distributions, water gas shift reaction rate, potential for carbon formation and electrochemistry were considered. A 2-D COMSOL® model was developed which included separate defined ...

Modeling the Electroplating of Hexavalent Chromium

N. Obaid[1], R. Sivakumaran[1], J. Lui[1], A. Okunade[1]
[1]University of Waterloo, Waterloo, ON, Canada

This project modeled an industrial chromium plating process for automotive components. The process was modeled via the COMSOL Multiphysics® Electrodeposition Module. The simulation examined the effect of solution conductivity, electrode spacing, and anode height utilizing a factorial design approach. A sensitivity analysis was used to study the effect of these variables on the thickness value at ...

Parameter Estimation in a Single Particle Model Using COMSOL Multiphysics® Software and MATLAB® Optimization

B. Rajabloo [1], M. Désilets [1], Y. Choquette [2],
[1] Département de Génie Chimique et de Génie Biotechnologique, Université de Sherbrooke, QC, Canada
[2] Institut de recherche d’Hydro-Québec, Varennes, QC, Canada

When it comes to study the behavior of the secondary batteries, physics-based models are more representative of the real behaviour than equivalent circuit models, especially for the estimation of the life and capacity fading. On the other hand, the complexity and computational cost of sophisticated physics-based models like pseudo two-dimensional (P2D) models justify the use of more simplified ...