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在所有电池系统中，锂氧电池的理论比能量最高，而实际比能量却明显不足。阻碍氧和/或电子传递导致多孔空气电极的有限利用，而实现对电化学和质量传递耦合的定量理解是具有挑战性的。本文首创了一种具有高度一致和可控通道单元的多孔电极，该电极排除了无序孔隙的随机性，从而能够研究控制机制。通过comsol建立了一个动态非均质模型，提供了LiO2的第一个时空分布，揭示了其在有限电子输运下的反向扩散轨迹。实验和模型的协同结合确定了通道尺寸在分为质量，杂交和电子传递控制的机制中的关键作用。对于大孔隙来说，提高Li2O2的导电性和减轻固液界面损伤比增强氧的扩散更为迫切 ... Mehr lesen
Ultrasonic nondestructive testing (NDT) is extensively used in fields like medicine, oil and gas, and aerospace to inspect materials without causing damage. However, developing experimental setups and prototypes can be costly and time-consuming. This study employs advanced computational ... Mehr lesen
压电材料在受到机械应力时会产生电压，这种性质使压电材料在声波传感器领域具有广泛应用。湿度的测量和把控广泛地应用于粮食贮存、气象预报与加工以及国防建设等各个领域。当今社会对各种成本低、性能优异的湿度传感器的需求正在日益上升。石英晶体微天平（QCM）具有高灵敏度、无需物理接触、体积小、易于集成等特点，通过在石英晶体微天平表面覆盖一层能够响应水分子的材料，可以监测环境中的湿度。这种材料能够吸收和解吸水分，从而改变石英晶体的质量，进而影响其共振频率。通过检测这一频率的变化，我们可以准确获取周围的相对湿度。本研究利用有限元软件COMSOL的多物理场耦合功能 ... Mehr lesen
Clayey soils and rocks are often used to secure contaminants, dissolved in the interstitial water, or fluids immiscible with water, because of their hydraulic properties (very low permeability and high water retention capabilities, see e.g. McCartney et al., 2016). However, their hydro ... Mehr lesen
High average power lasers are currently being designed for laser fusion applications. Single beamlines with laser amplifiers should be able to deliver up to 10 kW average power at 10-Hz repetition rate. For achieving a 5 to 10 % wall-plug efficiency, this means that at least, 50 kW will ... Mehr lesen
为了证明膨胀对电池厚度变化的影响，传统p2d模型耦合移动边界法新建立了一个模型。对复合材料的比例进行了详细分类，以准确分析两种材料对容量的贡献。此外，还研究了电极设计（如活性层厚度和负极孔隙率）以及工作条件对电池电化学性能和厚度变化的影响。当硅含量增加并改变电极结构时，容量贡献率从 85% 增加到 92%。当孔隙率从 40% 增加到 60% 以及负极活性层厚度从 55 μm 增加到 85 μm 时，容量利用率分别从 58% 到 79% 和从 68% 到 59% 不等。在速率测试中，当速率从 0.5 C 变化到 2 C 时，电池厚度变化从 2.49 μm 减小到 1.56 ... Mehr lesen
Bladder outlet obstruction (BOO) is a prevalent condition that characterises increased urethral resistance and gives rise to a myriad of lower urinary tract symptoms. Over time, BOO can significantly affect bladder functionality and lower quality of life. Furthermore, surgical ... Mehr lesen
In this study, a small scale direct solar thermal energy storage system with secondary reflector is designed and developed. The main advantage of thermal energy storage is that cooking can be carried out during the time when there is little or no sun shine. In addition, no heat transport ... Mehr lesen
Bentonite is a versatile material that is, among other things, envisaged in most countries worldwide for use in radioactive waste repositories to protect the waste canisters against groundwater. The thermo-hydro-mechanically (THM) coupled process of bentonite saturation is commonly based ... Mehr lesen
Soil sedimentation and consolidation, whether they are naturally or anthropically driven processes, are closely interconnected. While theoretical models are available to separately describe the behaviour of either ‘fluid’ suspensions or ‘solid’ soil, no well-established unified theory ... Mehr lesen