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Suchbegriff:

Batteries, Fuel Cells, and Electrochemical Processes

Effect of Intercalation Diffusivity When Simulating Mixed Electrode Materials in Li-Ion Batteries

E. Wikner [1],
[1] Chalmers University of Technology, Gothenburg, Sweden

This paper is about the influence of the diffusion coefficient when simulating mixed electrode materials. The results show that when simulating dynamic behavior of a lithium ion battery cell with mixed electrode material the diffusion coefficients is very important. Mehr lesen

Modeling and Simulation of Thermal Runaway in Cylindrical 18650 Lithium-Ion Batteries

A. M. Melcher [1], C. Ziebert [1], B. Lei [1], M. Rohde [2], H. J. Seifert [2]
[1] Karlsruhe Institute of Technology, IAM-AWP, Karlsruhe, Germany
[2] Karlsruhe Institute of Technology, Karlsruhe, Germany

In this work the coupled electrochemical-thermal model for a lithium-ion battery (LIB) based on porous electrode theory has been extended with contributions coming from exothermic side reactions based on an Arrhenius law to model abuse mechanisms, which could lead to a thermal runaway. ... Mehr lesen

Spectroscopic Modeling of Photoelectrochemical Water Splitting

P. Cendula [1], J. O. Schumacher [1],
[1] Institute of Computational Physics, Zurich University of Applied Sciences, Winterthur, Switzerland

A photoelectrochemical (PEC) cell uses solar energy to split water to hydrogen and oxygen in single integrated device. Electrochemical impedance spectroscopy is a suitable tool to characterize recombination and reaction mechanisms in PEC cell. Full numerical drift-diffusion calculations ... Mehr lesen

2D Axisymmetric Simulation of Pulsed Electrochemical Machining (PECM) of Internal Precision Geometries

M. Hackert-Oschätzchen [1], M. Kowalick [1], R. Paul [1], M. Zinecker [1], D. Kuhn [1], G. Meichsner [2], A. Schubert [3],
[1] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany
[2] Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany
[3] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany; Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany

This study presents investigations on a developed process design for manufacturing internal precision geometries by pulsed electrochemical machining (PECM) with help of multiphysics simulations. Therefore, a 2D axisymmetric transient model was created. The considered physical phenomena ... Mehr lesen

Transient Simulation of an Electrochemical Machining Process for Stamping and Extrusion Dies

M. Penzel [1], M. Hackert-Oschätzchen [2], M. Kreißig [1], M. Kowalick [1], M. Zinecker [1], A. Schubert [1], G. Meichsner [3],
[1] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany
[2] Professorship Micromanufacturing Technology, Technische Universität Chemnitz, Chemnitz, Germany; Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany
[3] Fraunhofer Institute for Machine Tools and Forming Technology, Chemnitz, Germany

Precise electrochemical machining (PEM) is a non-conventional machining technology, based on anodic dissolution of metallic work-pieces. In this study an additional extension of the precise electrochemical machining with a precise angle-controlled cylinder positioning is aimed. Due to ... Mehr lesen

Modeling and Simulation of Transient SECM (Scanning ElectroChemical Microscopy) Response of Porous Electrodes

L. Balboa [1], G. Wittstock [1],
[1] Institute of Chemistry, Carl v. Ossietzky Universität Oldenburg, Oldenburg, Germany

In the past two decades, highly porous nanostructured materials have been investigated and used for a large variety of applications, such as catalysis, energy conversion/storage, optics, sensing and more. Nanoporous gold (npAu) is one of such materials which have shown great potential as ... Mehr lesen

Aluminization Process from Ionic Liquid in Operative Conditions: Validation and Perspective

A. Giaccherini [1], E. Berretti [2], S. Martinuzzi [1], S. Caporali [1],
[1] INSTM, Firenze, Italy
[2] Department of Chemistry, University of Florence, Firenze, Italy

This work is a first evaluation of the validity of the frozen rotor approximation for the simulation of a stirred beaker. The agreement is good, further analysis will be carried before using the model to optimize labscale setup dedicated to IL electrochemistry. Mehr lesen

Modeling Migration-Diffusion-Reaction Processes in an Idealized Lithium-Sulfur Cell

G. Minton [1], R. Purkayastha [1], S. Walus [1], M. Marinescu [2], T. Zhang [2], G. Offer [2],
[1] Oxis Energy Ltd, Oxford, United Kingdom
[2] Imperial College London, London, United Kingdom

During the basic operation of a lithium-sulfur (Li-S) cell, sulfur molecules are required to undergo a complex mix of electrochemical and chemical reaction processes. To date, almost all modeling of Li-S cell behavior has been undertaken using electroneutral, structurally homogenized, ... Mehr lesen

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