Die Application Gallery bietet COMSOL Multiphysics® Tutorial- und Demo-App-Dateien, die für die Bereiche Elektromagnetik, Strukturmechanik, Akustik, Strömung, Wärmetransport und Chemie relevant sind. Sie können diese Beispiele als Ausgangspunkt für Ihre eigene Simulationsarbeit verwenden, indem Sie das Tutorial-Modell oder die Demo-App-Datei und die dazugehörigen Anleitungen herunterladen.
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Voltammetry is modeled at a microelectrode of 10um radius. In this common analytical electrochemistry technique, the potential at a working electrode is swept up and down and the current is recorded. The current-voltage waveform ("voltammogram") gives information about the reactivity and ... Mehr lesen
Zweck dieser App ist es, die Anwendung der Cyclovoltammetrie zu demonstrieren und zu simulieren. Sie können die Massenkonzentration beider Spezies, die Transporteigenschaften, die kinetischen Parameter sowie das Zyklusspannungsfenster und die Scanrate variieren. Die Cyclovoltammetrie ... Mehr lesen
Due to its high capacity, silicon (Si) is often added to graphite in the negative electrode of lithium-ion batteries. Silicon–graphite blended electrodes may exhibit significant thermodynamic voltage hysteresis (“path dependence”) because the equilibrium potential of the lithium–silicon ... Mehr lesen
This 2D model demonstrates how to model a galvanic couple in which the corrosion of the anode causes a geometry deformation. The parameter data used is for an Magnesium Alloy (AE44) - mild steel couple in brine solution (salt water). Mehr lesen
Electrochemical glucose sensors use amperometric methods to measure the concentration of glucose in a sample. This example models the diffusion of glucose and ferri/ferrocyanide redox mediators in a unit cell of electrolyte above an interdigitated electrode. The sensor gives a linear ... Mehr lesen
Rotating cylinder Hull cells are an important experimental tool in electroplating and electrodeposition and are used for the measurement of nonuniform current distribution, mass transport, and throwing power of plating baths. The model reproduces the results for a commercially available ... Mehr lesen
This model exemplifies the basic principles of crevice corrosion and how a time-dependent study can be used to simulate the electrode deformation. The model is in 2D and the polarization data for the corrosion reaction is taken from a paper by Absulsalam and others. The model and the ... Mehr lesen
A fuel cell unit cell is modeled using the full Butler-Volmer expression for the anodic and cathodic charge transfer reactions. The anodic and cathodic overpotentials depend on the local ionic and electronic potentials, which are obtained from the charge balance equations for ionic and ... Mehr lesen
This 3D model example demonstrates the use of the Primary Current Distribution interface for modeling current distributions in electrochemical cells. In primary current distribution, the potential losses due to electrode kinetics and mass transport are assumed to be negligible, and ... Mehr lesen
Lithium-sulfur (Li-S) batteries are used in niche applications with high demands for specific energy densities, which may be as high as 500-600 Wh/kg. The chemistry is fairly complex, since multiple polysulfide species participate in the various charge transfer reactions. The chemistry ... Mehr lesen