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In the diffuse double layer and within the first few nanometers of an electrode surface, the assumption of electroneutrality is not valid due to charge separation. Typically, the diffuse double layer may be of interest when modeling very thin layers of electrolyte including those in ... Mehr lesen
In a polymer electrolyte membrane fuel cell (PEMFC), water is produced at the cathode. The cell is also fed with water vapor via the inlet gas streams, in order to keep the polymer electrolyte membrane humidified. If the water partial pressure in the gas phase exceeds the vapor ... Mehr lesen
This example models galvanic corrosion between two different phases in a magnesium alloy for a representative cross-sectional microstructure configuration. The Phase Field interface is used here to model dissolution of a constituent phase leading to topological changes. The electrode ... Mehr lesen
In small PEM fuel cell systems (in the sub-100 W range) no active devices for cooling or air transport are normally used. This is due to the desire to minimize parasitic power losses from pumps and fans, and to reduce the system complexity, size, and cost. The reactants at the cathode ... Mehr lesen
Removing halogen groups from hydrocarbons is an important reaction step in several chemical processes. One application is water purification. Other examples involve organic synthesis, where the removal of halogen groups serves as a starting point for carbon-carbon coupling reactions. ... Mehr lesen
This tutorial demonstrates the Lumped Battery interface for modeling capacity loss in a battery. A set of lumped parameters are used to describe the capacity loss that occurs due to parasitic reactions in the battery, assuming no knowledge of the internal structure or design of the ... Mehr lesen
The present model example is based on Copper Deposition in a Trench model available in Electrodeposition Application Library. The nonuniform deposition along the trench surface leads to formation of a cavity/void. Since the Deformed Geometry interface cannot handle topological changes, ... Mehr lesen
This example was originally formulated by Albert Witarsa under Professor Bruce Finlayson’s supervision at the University of Washington in Seattle. It was part of a graduate course in which the assignment consisted of evaluating the potential of patents in the field of microfluidics ... Mehr lesen
Lithium-sulfur (Li-S) batteries are used in niche applications with high demands for specific energy densities, which may be as high as 500-600 Wh/kg. The chemistry is fairly complex, since multiple polysulfide species participate in the various charge transfer reactions. The chemistry ... Mehr lesen
This example models cathodic protection of a steel reinforcing bar in concrete. Three different electrochemical reactions are considered on the steel surface. Charge and oxygen transport are modeled in the concrete domain, where the electrolyte conductivity and oxygen diffusivity depend ... Mehr lesen